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http://repositorio.yachaytech.edu.ec/handle/123456789/839| Title: | Synthesis of N-benzyloxyphthalimides (NBOPIs) and their potential application in C(sp3)-C(sp3) bond generation |
| Authors: | Palma Cando, Alex Uriel Chiliquinga Aguilar, Sixto Isaí |
| Keywords: | N-benciloxiftalimidas Voltamperometría cíclica Electrólisis N-benzyloxyphthalimides Cyclic voltammetry Bulk electrolysis |
| Issue Date: | Oct-2024 |
| Publisher: | Universidad de Investigación de Tecnología Experimental Yachay |
| Abstract: | En este trabajo se reporta la estrategia sintética utilizada para la construcción de dos N-benciloxiftalimidas y sus tendencias de reactividad en condiciones electroreductoras. Los sustratos sintetizados fueron caracterizados completamente mediante técnicas espectroscópicas y se analizó su comportamiento electroquímico mediante voltamperometría cíclica. Se llevaron a cabo experimentos de electrólisis en uno de los sustratos y demostraron que la reactividad cambia drásticamente según el disolvente utilizado. Del mismo modo, el uso de electrodos o aditivos que controlen la reacción de oxidación que tiene lugar en el ánodo también demostró modificar la reactividad observada. |
| Description: | In this work, the synthetic strategy used for the construction of two N-benzyloxyphthalimides and their reactivity tendences in electroreductive conditions is reported. The synthesized substrates were completely characterized by spectroscopic techniques and their electrochemical behavior was analyzed using cyclic voltammetry. Bulk electrolysis experiments were carried out in one of the substrates and demonstrated that reactivity changes drastically depending on the solvent used. As well, using electrodes or additives that controls the oxidation reaction taking place at the anode also showed to modify the observed reactivity. |
| URI: | http://repositorio.yachaytech.edu.ec/handle/123456789/839 |
| Appears in Collections: | Química |
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