Synthesis of N-alkoxy phthalimides and their electrochemical behavior

Patiño Alonzo, Erick Steven

Please use this identifier to cite or link to this item: http://repositorio.yachaytech.edu.ec/handle/123456789/139

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DC Field	Value	Language
dc.contributor.advisor	Palma Cando, Alex Uriel	-
dc.contributor.advisor	Frontana Uribe, Bernardo Antonio	-
dc.contributor.author	Patiño Alonzo, Erick Steven	-
dc.date.accessioned	2020-07-09T22:48:23Z	-
dc.date.available	2020-07-09T22:48:23Z	-
dc.date.issued	2020-02	-
dc.identifier.uri	http://repositorio.yachaytech.edu.ec/handle/123456789/139	-
dc.description	In this work, the synthesis of four N-alkoxy phthalimides and their electrochemical behavior is reported. Diphenyl methanol, geraniol, benzyl alcohol and 2-phenoxyethanol were used to synthesize the desired products under Mitsunobu conditions. Additionally, a protocol of tosylation-nucleophilic displacement was applied to benzyl alcohol and 2-phenoxyethanol for the same purpose. Cyclic voltammetry experiments in ACN and DMF 0.1M TBAP were suitable media to determine the reduction potential of such species. A few bulk electrolysis experiments showed the formation of tributylamine and several other products that appear in this works as proposed structures rather than confirmed.	es
dc.description.abstract	En este trabajo se reporta la síntesis de cuatro N-alcoxi ftalimidas y su comportamiento electroquímico. Difenil metanol, geraniol, alcohol bencílico y 2-fenoxietanol fueron usados para sintetizar los productos de interés en condiciones de Mitsunobu. Adicionalmente, se siguió una estrategia de tosilación y desplazamiento nucleofílico con alcohol bencílico y 2-fenoxietanol para el mismo fin. Los potenciales de reducción de estas especies fueron determinados mediante experimentos de voltametria cíclica en ACN y DMF 0.1M TBAP. Experimentos de electrólisis mostraron la formación de tributilamina en conjunto con otras especies que aquí se proponen mas no han sido confirmadas.	es
dc.language.iso	eng	es
dc.publisher	Universidad de Investigación de Tecnología Experimetal Yachay	es
dc.rights	openAccess	es
dc.subject	N-alcoxi ftalimidas	es
dc.subject	Electrolisis	es
dc.subject	Voltametria cíclica	es
dc.subject	Mitsunobu	es
dc.subject	N-alkoxy phthalimide	es
dc.subject	Bulk electrolysis	es
dc.subject	Cyclic voltammetry	es
dc.title	Synthesis of N-alkoxy phthalimides and their electrochemical behavior	es
dc.type	bachelorThesis	es
dc.description.degree	Químico/a	es
dc.pagination.pages	73 páginas	es
Appears in Collections:	Química

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