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http://repositorio.yachaytech.edu.ec/handle/123456789/139| Title: | Synthesis of N-alkoxy phthalimides and their electrochemical behavior |
| Authors: | Palma Cando, Alex Uriel Frontana Uribe, Bernardo Antonio Patiño Alonzo, Erick Steven |
| Keywords: | N-alcoxi ftalimidas Electrolisis Voltametria cíclica Mitsunobu N-alkoxy phthalimide Bulk electrolysis Cyclic voltammetry |
| Issue Date: | Feb-2020 |
| Publisher: | Universidad de Investigación de Tecnología Experimetal Yachay |
| Abstract: | En este trabajo se reporta la síntesis de cuatro N-alcoxi ftalimidas y su comportamiento electroquímico. Difenil metanol, geraniol, alcohol bencílico y 2-fenoxietanol fueron usados para sintetizar los productos de interés en condiciones de Mitsunobu. Adicionalmente, se siguió una estrategia de tosilación y desplazamiento nucleofílico con alcohol bencílico y 2-fenoxietanol para el mismo fin. Los potenciales de reducción de estas especies fueron determinados mediante experimentos de voltametria cíclica en ACN y DMF 0.1M TBAP. Experimentos de electrólisis mostraron la formación de tributilamina en conjunto con otras especies que aquí se proponen mas no han sido confirmadas. |
| Description: | In this work, the synthesis of four N-alkoxy phthalimides and their electrochemical behavior is reported. Diphenyl methanol, geraniol, benzyl alcohol and 2-phenoxyethanol were used to synthesize the desired products under Mitsunobu conditions. Additionally, a protocol of tosylation-nucleophilic displacement was applied to benzyl alcohol and 2-phenoxyethanol for the same purpose. Cyclic voltammetry experiments in ACN and DMF 0.1M TBAP were suitable media to determine the reduction potential of such species. A few bulk electrolysis experiments showed the formation of tributylamine and several other products that appear in this works as proposed structures rather than confirmed. |
| URI: | http://repositorio.yachaytech.edu.ec/handle/123456789/139 |
| Appears in Collections: | Química |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| ECQI0017.pdf | 3.03 MB | Adobe PDF | View/Open |
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